Section 12C Acid-base Certain hydrogen-containing molecules or ions react by transferring a hydrogen ion, H+, to another molecule or ion. Example:
A hydrogen ion, H+, is just a proton, and these acid-base reactions are called proton transfer reactions. An acid is defined as a proton donor and a base is defined as a proton acceptor. This is the Brønsted-Lowry definition. A base must have a non-bonding pair of electrons which can be used to form a bond with a proton. Brønsted acid: a proton donor, i.e. a species which donates a proton in a chemical reaction Example: HCl in the above examples. Brønsted base: a proton acceptor, i.e a species which accepts a proton in a chemical reaction Oxonium (hydronium ion): the cation H3O+, often written as H+(aq) or just H+ in equations in water (water, aqua, aq). Hydroxide ion: the anion HO¯ (more commonly written OH¯, but it is O which has the formal charge of 1). Conjugate acids and bases: When an acid loses a proton, its product is called the conjugate base of that acid. When a base accepts a proton its conjugate acid is formed Neutralisation: The reaction between an acid and a base Salt: the product (other than water) of a neutralisation reaction between an acid and a base. Salts are ionic compounds Alkali: Aqueous solution of a base |