Curnow Research Group
Welcome to the Curnow Research Group
Left to right:Tim Huber, Owen Curnow, Michael Holmes, Ruhamah Yunis, Kelvin Walst
In our research website pages you will find details of our research group. We are based in the Department of Chemistry at the University of Canterbury, Christchurch, New Zealand.
Our group is currently focussed on two aspects of green chemistry. The major focus is on developing an entirely new class of ionic liquids (ILs) based on amino-stabilised cyclopropenium cations. This involves the synthesis of new cations with a particular interest in those that have low melting points and viscosity. ILs have a vast range of potential applications: battery electrolytes, novel solvents, chiral solvents, fuel cells, dye-sensitised solar cells, carbon dioxide absorption, hydrogen storage, chromatography (as a non-volatile support), catalysis etc. Our group aims to design ILs that have properties useful for particular applications. The second focus is on the use of the TAML® catalyst system for the purification of gases. This catalyst is most commonly used for the oxidation of organics using hydrogen peroxide.
We are also interested in the structures of chloride hydrates, [Cl(H2O)n]– and [Cl2(H2O)n]2–.
Two of our ionic liquids are now available for purchase through Sigma-Aldrich:
- 1,2,3-Tris(diethylamino)cyclopropenylium bis(trifluoromethanesulfonyl)imide, [C3(NEt2)3][N(SO2CF3)2]
- 1,2,3-Tris(diethylamino)cyclopropenylium dicyanamide, [C3(NEt2)3][N(CN)2]
Our first two publications on ionic liquids are now in print:
Triaminocyclopropenium salts as ionic liquids: Owen J. Curnow, Douglas R. MacFarlane, Kelvin J. Walst, Chem. Commun., 2011, 47, 10248–10250. http://xlink.rsc.org/?doi=C1CC13979G
A facile route to functionalised, protic and chiral ionic liquids based on the triaminocyclopropenium cation: Owen J. Curnow,* Michael T. Holmes, Leonardus C. Ratten, Kelvin J. Walst and Ruhamah Yunis, RSC Advances, 2012, 2, 10794–10797. http://xlink.rsc.org/?doi=C2RA22078D
A general review on ionic liquids has appeared in Chemistry in New Zealand:
Ionic liquids: Some of their remarkable properties and some of their applications: Owen J. Curnow, Chemistry in New Zealand, 2012, 76, 118–122.
We do not currently have any funding to support either Postdocs, or PhD students. However we are actively looking for prospective PhD students,who should therefore apply for a University scholarship to fund their studies. Please contact Owen Curnow by email if this is the case.
- See the AAILS website for conferences: http://www.aails.com/index.asp